When I went to the documentation there seemed to be very little about how to get information in and out using PHP, and a number of people asking for client examples.
Here is a little test page that I did that will return the results of the echo sample that is on the service website. I decided to use the pear xml_rpc2 library as it seems to be the most straight forward to use.
<? php
// I am using the new pear RPC2 library as it seems the simplest to use
// Go here for more info:
// http://pear.php.net/package/XML_RPC2
require_once 'XML/RPC2/Client.php';
// This is the drupal URL for the services module XMLRPC server
$server = 'http://localhost/~bstewart/points/?q=services/xmlrpc';
// The options we want to pass to the server. Prefix is required. You don't need debug.
// Moreinformation here:
// http://pear.php.net/manual/en/package.webservices.xml-rpc2.client.php
$options = array(
'prefix' => 'echo.',
'debug' => TRUE
);
//// You can create and add $options array to this call for debug and other options related to the call.
$client = XML_RPC2_Client::create($server, $options);
//
//// Execute and get the resulting details
$resp = $client->echo("It Works !!!");
//
// Display the message onscreen
echo $resp[message];
?>